Probing the nanohydrodynamics at liquid-solid interfaces using thermal motion

We report on a new method to characterize nano-hydrodynamic properties at the liquid/solid interface relying solely on the measurement of the thermal motion of confined colloids. Using Fluorescence Correlation Spectroscopy (FCS) to probe the diffusion of the colloidal tracers, this optical technique --equivalent in spirit to the microrheology technique used for bulk properties-- is able to achieve nanometric resolution on the slip length measurement. It confirms the no-slip boundary condition on wetting surfaces and shows a partial slip b=18 +/- 5 nm on non-wetting ones. Moreover, in the absence of external forcing, we do not find any evidence for large nano-bubble promoted slippage on moderately rough non-wetting surfaces.Comment: 4 pages, 3 figure

Wetting on Nanorough Surfaces

We present in this Letter a free-energy approach to the dynamics of a fluid near a nanostructured surface. The model accounts both for the static phase equilibrium in the vicinity of the surface (wetting angles, Cassie-Wenzel transition) and the dynamical properties like liquid slippage at the boundary. This method bridges the gap between phenomenological phase-field approaches and more macroscopic lattice-Boltzmann models

Exponential decay for the damped wave equation in unbounded domains

We study the decay of the semigroup generated by the damped wave equation in an unbounded domain. We first prove under the natural geometric control condition the exponential decay of the semigroup. Then we prove under a weaker condition the logarithmic decay of the solutions (assuming that the initial data are smoother). As corollaries, we obtain several extensions of previous results of stabilisation and control

Numerical aspects of nonlinear Schrodinger equations in the presence of caustics

The aim of this text is to develop on the asymptotics of some 1-D nonlinear Schrodinger equations from both the theoretical and the numerical perspectives, when a caustic is formed. We review rigorous results in the field and give some heuristics in cases where justification is still needed. The scattering operator theory is recalled. Numerical experiments are carried out on the focus point singularity for which several results have been proven rigorously. Furthermore, the scattering operator is numerically studied. Finally, experiments on the cusp caustic are displayed, and similarities with the focus point are discussed.Comment: 20 pages. To appear in Math. Mod. Meth. Appl. Sc

Diffusion in pores and its dependence on boundary conditions

We study the influence of the boundary conditions at the solid liquid interface on diffusion in a confined fluid. Using an hydrodynamic approach, we compute numerical estimates for the diffusion of a particle confined between two planes. Partial slip is shown to significantly influence the diffusion coefficient near a wall. Analytical expressions are derived in the low and high confinement limits, and are in good agreement with numerical results. These calculations indicate that diffusion of tagged particles could be used as a sensitive probe of the solid-liquid boundary conditions.Comment: soumis \`a J.Phys. Cond. Matt. special issue on "Diffusion in Liquids, Polymers, Biophysics and Chemical Dynamics

Effective temperatures of a heated Brownian particle

We investigate various possible definitions of an effective temperature for a particularly simple nonequilibrium stationary system, namely a heated Brownian particle suspended in a fluid. The effective temperature based on the fluctuation dissipation ratio depends on the time scale under consideration, so that a simple Langevin description of the heated particle is impossible. The short and long time limits of this effective temperature are shown to be consistent with the temperatures estimated from the kinetic energy and Einstein relation, respectively. The fluctuation theorem provides still another definition of the temperature, which is shown to coincide with the short time value of the fluctuation dissipation ratio

Inelastic X-ray scattering from valence electrons near absorption edges of FeTe and TiSe2_2

We study resonant inelastic x-ray scattering (RIXS) peaks corresponding to low energy particle-hole excited states of metallic FeTe and semi-metallic TiSe$_2$ for photon incident energy tuned near the $L_{3}$ absorption edge of Fe and Ti respectively. We show that the cross section amplitudes are well described within a renormalization group theory where the effect of the core electrons is captured by effective dielectric functions expressed in terms of the the atomic scattering parameters $f_1$ of Fe and Ti. This method can be used to extract the dynamical structure factor from experimental RIXS spectra in metallic systems.Comment: 6 pages, 4 figure

Geometric optics and instability for semi-classical Schrodinger equations

We prove some instability phenomena for semi-classical (linear or) nonlinear Schrodinger equations. For some perturbations of the data, we show that for very small times, we can neglect the Laplacian, and the mechanism is the same as for the corresponding ordinary differential equation. Our approach allows smaller perturbations of the data, where the instability occurs for times such that the problem cannot be reduced to the study of an o.d.e.Comment: 22 pages. Corollary 1.7 adde